Key vocabulary for first time learners:

www.heinsuniverse.com/afrikaans.html

Afrikaans books on Google Books
Google's offering

Charts of personal and possessive pronouns in Afrikaans and Dutch, for comparison.
http://home.unilang.org/main/wiki2/index.php/Pronouns_in_Afrikaans

Quick verb conjugation tutorial, with examples.
http://www.ultrasw.com/pawlowski/brendan/Afrikaans%20Verbs.html

Verbix- type in a verb in Afrikaans, and the program will conjugate it for you:
http://www.verbix.com/languages/afrikaans.shtml

http://en.wikipedia.org/wiki/Afrikaans_grammar

http://www.experiencefestival.com/a/Afrikaans/id/1904509

Pronunciation Key:
http://www.mieliestronk.com/afrkey.html

Explaining Pronunciation:
http://www.omniglot.com/writing/afrikaans.htm